How to wear a tallit: Different customs
The blessing blessing recited before donning a tallit is not on the tallit, per se, but on the tzitzit, which are the essence of the mitzvah. The tallit is really just our way of fulfilling the mitzvah of wrapping ourselves in a tzitzit garment. The wording of the Tzitzit Blessing is ...l'hit'atef b'tzitzit, i.e....